1st Couple: Jeremy and Anna

2nd Couple: Tyler and Caroline

3rd Couple: Stefan and Elena

4th Couple: Klaus and Caroline

5th Couple: Stefan and Katherine

6th Couple: Damon and Elena

7th Couple: Damon and Rebekah

8th Couple: Stefan and Rebekah

9th Couple: Damon and Katherine

10th Couple: Bonnie and Jeremy

11th Couple: Bonnie and Jamie

12th Couple: Caroline and Matt

*I listed them as well, if you forgot

ADDED DAMON AND ROSE, ALARIC AND JENNA, ALARIC AND MEREDITH