1st Couple: Jeremy and AnnaEdit

2nd Couple: Tyler and CarolineEdit

3rd Couple: Stefan and ElenaEdit

4th Couple: Klaus and CarolineEdit

5th Couple: Stefan and KatherineEdit

6th Couple: Damon and ElenaEdit

7th Couple: Damon and RebekahEdit

8th Couple: Stefan and RebekahEdit

9th Couple: Damon and KatherineEdit

10th Couple: Bonnie and JeremyEdit

11th Couple: Bonnie and JamieEdit

12th Couple: Caroline and MattEdit

*I listed them as well, if you forgotEdit

ADDED DAMON AND ROSE, ALARIC AND JENNA, ALARIC AND MEREDITH